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- W2003898051 abstract "The interactions of vapor-deposited methanol, ethanol, 1-propanol, and 1-hexanol with an 11-mercaptoundecanoic acid (HOOC(CH2)10SH) self-assembled monolayer adsorbed on a nickel(111) single crystal were studied in ultrahigh vacuum by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). The peak shapes of the TPD spectra for methanol, ethanol, and propanol desorption are similar, suggesting that these alcohols undergo similar desorption processes. Their peak desorption temperatures at the lowest submonolayer fluences increased with the number of carbons in the alcohol, suggesting that the methyl and methylene groups, as well as the hydroxyl group, participate in the adsorbed alcohol monolayer's interactions at the acid-terminated self-assembled monolayer surface. Threshold TPD (TTPD) was used for a quantitative analysis of the desorption spectra as a function of coverage. The structure and behavior of hexanol's desorption spectra suggest a different desorption process than its lower-molecular-weight analogues. Of all the alcohols studied, hexanol exhibited the strongest interaction with the acid-terminated surface. The desorption energies calculated by the TTPD method for the straight-chain n-alcohols C1−C3 (15−20 kJ mol-1) and C6 (∼38 kJ mol-1) in the submonolayer regime were in the range expected (10−40 kJ mol-1) for hydrogen bonding." @default.
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- W2003898051 date "1999-03-23" @default.
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- W2003898051 title "Interfacial Interactions between a Carboxyl-Terminated Monolayer and Various <i>n</i>-Alcohols" @default.
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- W2003898051 doi "https://doi.org/10.1021/la980940l" @default.
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