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- W2003929227 abstract "A one-step electroless plating method was applied to synthesize a series of TiO2 (activated by Ag) supported W modified CoB catalysts for H2 generation from hydrolysis of NaBH4. The modification amount of W was optimized and the highest H2 generation rate reached 7.27 L min−1 (g Co)−1 in 1 wt% NaBH4 solution (with 5 wt% NaOH as stabilizer) at 293 K, nearly 16% improvement over the undoped 3CoB/Ag–TiO2 catalyst. The catalytic activity was comparable with some noble metal catalysts. The catalyst could retain ∼50% of initial activity after 5 runs and was stable in ambient air. Further characterizations revealed that the high dispersion of W–CoB, the distinct mesoporous structure inherited from TiO2 support and the electron interactions among Co0, B0 and W0 might account for the high performance. The tungsten oxide existed on the surface of catalysts could act as Lewis acid to facilitate the adsorption of BH4− ions, which would further enhance the catalytic performance." @default.
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- W2003929227 date "2015-05-01" @default.
- W2003929227 modified "2023-10-14" @default.
- W2003929227 title "W-modified CoB supported on Ag-activated TiO 2 for hydrogen generation from alkaline NaBH 4 solution" @default.
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- W2003929227 doi "https://doi.org/10.1016/j.ijhydene.2015.03.092" @default.
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