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• W2003934439 abstract "We investigate the morphology of Cu films electrodeposited onto silicon from an acidic sulfate electrolyte with the addition of a variable concentration of chloride anions. Addition of chloride increases grain size and the degree of grain faceting while decreasing the density of growth nuclei. Well-developed monocrystalline dendrites are formed in acidic sulfate solutions with high concentration of chloride. Dendrites form under growth conditions that either approach diffusion limitation, or occur within a potential range where different crystallographic faces exhibit a different potential dependence for chloride desorption. The presence of dendrites however is mainly related to the fact that the reduction route Cu2+ → CuCl → Cu becomes the rate-determining process in solutions with high chloride concentration; the rate of this reaction is largest at {110} planes, where the concentration of chloride anions is the highest, generating dendrites with branches along the {110} directions." @default.
• W2003934439 created "2016-06-24" @default.
• W2003934439 creator A5006750451 @default.
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• W2003934439 date "2009-05-13" @default.
• W2003934439 modified "2023-09-30" @default.
• W2003934439 title "Dendritic Growth and Morphology Selection in Copper Electrodeposition from Acidic Sulfate Solutions Containing Chlorides" @default.
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• W2003934439 doi "https://doi.org/10.1021/jp8095456" @default.
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