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- W2003951021 abstract "Treatment of Os(Bcat)Cl(CO)(PPh3)2 (1; Bcat = B-1,2-O2C6H4) with AgSbF6 in THF removes chloride and gives a cationic boryl complex formulated as [Os(Bcat)(CO)(THF)2(PPh3)2]SbF6. This in turn when treated in situ with NCMe gives [Os(Bcat)(CO)(NCMe)2(PPh3)2]SbF6 (2). Complex 2 reacts with CO or CN-p-tolyl with displacement of the acetonitrile ligand trans to boryl to give [Os(Bcat)(CO)(MeCN)L(PPh3)2]SbF6, (L = CO (3), CN-p-tolyl (4)). Complex 1 also reacts directly with the anionic ligands formate, nitrite, and diethyldithiocarbamate to give the corresponding neutral 6-coordinate complexes Os(Bcat)(η2-O2CH)(CO)(PPh3)2 (5), Os(Bcat)(η2-O2N)(CO)(PPh3)2 (6), and Os(Bcat)(η2-S2CNEt2)(CO)(PPh3)2 (7). The crystal structures of 1, 2, 4, and 7 have been determined." @default.
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- W2003951021 date "1998-10-01" @default.
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- W2003951021 title "Crystal Structure of Os(Bcat)Cl(CO)(PPh<sub>3</sub>)<sub>2</sub> and the Syntheses and Structural Studies of Derived Cationic and Neutral Osmium Boryl Complexes" @default.
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- W2003951021 doi "https://doi.org/10.1021/om980524w" @default.
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