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- W2003992012 abstract "In order to gain some insight into the stability of configuration and the bonding in the novel disulfide-containing complex [(η-C5H5)2Fe2S2(SC2H5)2], electrochemical properties of this compound and its SCH3 and SCH2C6H5 analogues were studied in various solvents and the magnetic properties of a subsequently isolated paramagnetic monocation were investigated. The cyclic voltammogram of [(η-C5H5)2Fe2S2(SC2H5)2] shows a reversible one-electron oxidation at E12= +0.21 V and a quasi-reversible one-electron oxidation at E12 = +0.90 V (vs.saturated calomel electrode). The stable monocation has been electrochemically synthesized and the magnetic suceptibility shows a simple paramagnetic behavior with one unpaired electron per dimeric unit. Frozen solutions of this species at 103K yielded anisotropic ESR spectra with g1 = 2.135, g2 = 1.976, and g3 = 1.934. Labeling the complex with 33S in the disulfide bridge resulted in no observable hyperfine splitting or line broadening in the ESR. The dicationic species is unstable with respect to loss of the S2 bridge and formation of a solvent-ligated dication, [(η-C5H5)Fe(NCCH3)(SC2H5)]22+, isolated by electrolysis of the monocation at +1.2 V in CH3CN." @default.
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- W2003992012 date "1976-08-01" @default.
- W2003992012 modified "2023-09-24" @default.
- W2003992012 title "Electrochemistry of the iron-sulfur cluster compound [(η-C5H5)2Fe2S2(SC2H5)2]. Synthesis and propeties of the oxidation products" @default.
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- W2003992012 doi "https://doi.org/10.1016/s0022-328x(00)87987-5" @default.
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