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- W2003994672 abstract "The characteristic function of the polyelectrolyte chains is given, extending the mode expansion method applied in polyelectrolytes. The mean square end-to-end distance and the expansion factor 〈α2〉 are discussed. Although the dependence of the expansion factor on the salt concentration Cs and on the molecular weight M of the polymer is expressed as 〈α2〉−1 proportional to M1/2/Cs in the excess salt limit, it is suggested that under finite salt conditions the Cs dependence is modified to be of the Cs−1+ε type, with ε≳0. This behavior indicates that the counterion distribution around a polyion reduces the polymer expansion. This tendency agrees with experiments." @default.
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- W2003994672 date "1976-03-01" @default.
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- W2003994672 title "Chain statistics of polyelectrolytes" @default.
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- W2003994672 doi "https://doi.org/10.1063/1.432440" @default.
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