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• W2003997733 abstract "The first luminescent rhenium(I)–gold(I) hetero organometallics, Re{phenAu(PPh3)}(CO)3Cl (3) and Re{(PPh3)AuphenAu(PPh3)}(CO)3Cl (4), have been prepared using the gold(I) complex AuCl(PPh3) (PPh3 = triphenylphosphine) and the novel rhenium(I) complexes Re(phenH)(CO)3Cl (5) (phenH = 3-ethynyl-1,10-phenanthroline) or Re(HphenH)(CO)3Cl (6) (HphenH = 3,8-bis(ethynyl)-1,10-phenanthroline). All the present rhenium(I) complexes 3–6 were revealed to possess a facial configuration (fac-isomer) with respect to the three carbonyl ligands. The main frameworks for these new gold(I) organometallics were constructed by the Au–C σ-bonding (with the η1-type coordination) between the ethynylphenanthrolines and the Au(I) phosphine unit. Re(I)–Au(I) heterometallics 3 and 4 have shown single phosphorescence from the 3MLCT excited state and this observation can be interpreted in terms of the efficient intramolecular energy transfer from the Au(I) unit to the Re(I) unit." @default.
• W2003997733 created "2016-06-24" @default.
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• W2003997733 date "2004-09-01" @default.
• W2003997733 modified "2023-10-15" @default.
• W2003997733 title "Luminescent rhenium(I)–gold(I) hetero organometallics linked by ethynylphenanthrolines" @default.
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• W2003997733 doi "https://doi.org/10.1016/j.jorganchem.2004.06.026" @default.
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