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• W2003997889 abstract "The phenomenological crystal-field parameters of ${mathrm{Eu}}^{3+}$ in ${mathrm{Y}}_{2}$${mathrm{O}}_{3}$ are determined with reference to previous symmetry assignments obtained for the $^{7}F_{J}$ ($J=1 mathrm{to} 4$) sublevels by laser-induced polarized fluorescence. The crystal-field plus spin-orbit Hamiltonian is diagonalized on the truncated basis containing the lowest $^{7}F$ multiplet of the ${f}^{6}$ configuration. The final mean deviation of the experimental and calculated values is equal to 4.8 ${mathrm{cm}}^{ensuremath{-}1}$. The results are interpreted on the basis of the electrostatic model including point-charge and dipolar contributions. A possible complementary covalency contribution is found by application of the angular overlap model." @default.
• W2003997889 created "2016-06-24" @default.
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• W2003997889 creator A5040698159 @default.
• W2003997889 date "1981-09-15" @default.
• W2003997889 modified "2023-09-24" @default.
• W2003997889 title "Crystal-field analysis of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>Eu</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>doped in cubic yttrium sesquioxide. Application of the electrostatic and angular overlap models" @default.
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• W2003997889 doi "https://doi.org/10.1103/physrevb.24.3138" @default.
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