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- W2004014737 abstract "Abstract Rhodium(III) ion (Rh 3+ )-modified TiO 2 (Rh 3+ /TiO 2 ) samples having various physical properties and structures (anatase and rutile) were prepared using commercially available TiO 2 samples. Thus-prepared Rh 3+ /TiO 2 samples were used for degradation of acetaldehyde or mineralization of acetone with a constant vapor pressure under irradiation of visible light and correlations between the photocatalytic activities and physical properties were investigated. Rhodium(III) ion on the surface of TiO 2 worked as an inorganic photosensitizer and the Rh 3+ /TiO 2 samples showed a kind of volcano-like tendency against specific surface area of TiO 2 , indicating that the balance of surface area and crystallinity of TiO 2 is important in an Rh 3+ /TiO 2 photocatalyst. The latter reaction system was found to be a simple and convenient method to evaluate the activity of a photocatalyst in a short time. The role of Rh 3+ as a catalyst for multi-electron reduction of oxygen is discussed on the basis of results obtained for Rh 3+ -modified rutile-type TiO 2 samples." @default.
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- W2004014737 date "2011-04-01" @default.
- W2004014737 modified "2023-09-25" @default.
- W2004014737 title "Photocatalytic mineralization of volatile organic compounds over commercial titanium(IV) oxide modified with rhodium(III) ion under visible light irradiation and correlation between physical properties and photocatalytic activity" @default.
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- W2004014737 doi "https://doi.org/10.1016/j.cattod.2010.10.064" @default.
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