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• W2004017776 endingPage "468" @default.
• W2004017776 startingPage "456" @default.
• W2004017776 abstract "The water oxidising enzyme, photosystem II, performs one of the most important reactions for life on Earth. Today, in the context of finding renewable sources of energy as alternatives for fossil fuels, the four-electron oxidation of water using light energy stands as one of the most challenging reactions for scientists to understand and reproduce. Mastering this reaction is considered to be a key step towards the use of water and sunlight to produce renewable hydrogen. It is therefore not only timely but also urgent to understand the mechanism of this enzyme so that this understanding can be used to design artificial catalysts. A chemical catalyst that shares the property of the enzyme in its ability to oxidize water with a low overpotential, could greatly improve the efficiency of water electrolysis and photolysis. Here we briefly describe aspects of the enzyme focusing on the essential cofactors involved in the light driven oxidation of water and provide an overview of the work done to produce a biomimetic photocatalyst for water oxidation. The development of such a device can be conceptualized as the association of two chemical modules, a photoactive unit and a catalytic unit. The candidate of choice for the photoactive unit, at least on a proof-of-principle basis, is [Ru(bpy)3]2+. This is due to its robustness, its synthetic flexibility and its unique photophysical properties. The elusive manganese catalyst acting as the catalytic site is dealt with in the previous chapters of this issue. In this review we discuss the different challenges that must be met to develop a synthetic system for water photolysis. These include (1) efficient light absorption by a sensitizer, (2) development of a stable charge separating device, (3) vectorial electron flow to/from, (3a) a donor site that must be capable to accumulate charges for consequent catalytic reactions, and (3b) an acceptor system that allows a multi-electron process." @default.
• W2004017776 created "2016-06-24" @default.
• W2004017776 creator A5060925313 @default.
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• W2004017776 creator A5079144541 @default.
• W2004017776 creator A5079892264 @default.
• W2004017776 creator A5085421800 @default.
• W2004017776 date "2008-02-01" @default.
• W2004017776 modified "2023-10-18" @default.
• W2004017776 title "Artificial systems related to light driven electron transfer processes in PSII" @default.
• W2004017776 cites W1592246154 @default.
• W2004017776 cites W1926074116 @default.
• W2004017776 cites W1963796424 @default.
• W2004017776 cites W1966157057 @default.
• W2004017776 cites W1967250117 @default.
• W2004017776 cites W1969024947 @default.
• W2004017776 cites W1972857489 @default.
• W2004017776 cites W1973509459 @default.
• W2004017776 cites W1973721002 @default.
• W2004017776 cites W1976391206 @default.
• W2004017776 cites W1978006523 @default.
• W2004017776 cites W1978085924 @default.
• W2004017776 cites W1981989568 @default.
• W2004017776 cites W1986227479 @default.
• W2004017776 cites W1988875463 @default.
• W2004017776 cites W1993293065 @default.
• W2004017776 cites W1995067163 @default.
• W2004017776 cites W1995500119 @default.
• W2004017776 cites W1995994720 @default.
• W2004017776 cites W1996429242 @default.
• W2004017776 cites W1998777805 @default.
• W2004017776 cites W2010787074 @default.
• W2004017776 cites W2012046411 @default.
• W2004017776 cites W2012501847 @default.
• W2004017776 cites W2016349291 @default.
• W2004017776 cites W2017743572 @default.
• W2004017776 cites W2018306196 @default.
• W2004017776 cites W2023544689 @default.
• W2004017776 cites W2025854869 @default.
• W2004017776 cites W2026033505 @default.
• W2004017776 cites W2027580421 @default.
• W2004017776 cites W2029534741 @default.
• W2004017776 cites W2030863844 @default.
• W2004017776 cites W2032922463 @default.
• W2004017776 cites W2033260469 @default.
• W2004017776 cites W2035781859 @default.
• W2004017776 cites W2038012332 @default.
• W2004017776 cites W2039620058 @default.
• W2004017776 cites W2040461143 @default.
• W2004017776 cites W2042468885 @default.
• W2004017776 cites W2042718393 @default.
• W2004017776 cites W2043590390 @default.
• W2004017776 cites W2045343323 @default.
• W2004017776 cites W2045518428 @default.
• W2004017776 cites W2051502181 @default.
• W2004017776 cites W2052752040 @default.
• W2004017776 cites W2054959845 @default.
• W2004017776 cites W2060436795 @default.
• W2004017776 cites W2064791480 @default.
• W2004017776 cites W2065289609 @default.
• W2004017776 cites W2066055906 @default.
• W2004017776 cites W2069485800 @default.
• W2004017776 cites W2069506896 @default.
• W2004017776 cites W2071104521 @default.
• W2004017776 cites W2072369418 @default.
• W2004017776 cites W2073280624 @default.
• W2004017776 cites W2074108897 @default.
• W2004017776 cites W2074144594 @default.
• W2004017776 cites W2074916400 @default.
• W2004017776 cites W2075221211 @default.
• W2004017776 cites W2076104989 @default.
• W2004017776 cites W2076105421 @default.
• W2004017776 cites W2076169614 @default.
• W2004017776 cites W2081146558 @default.
• W2004017776 cites W2082889226 @default.
• W2004017776 cites W2083907491 @default.
• W2004017776 cites W2089049396 @default.
• W2004017776 cites W2089917194 @default.
• W2004017776 cites W2089921133 @default.
• W2004017776 cites W2091432638 @default.
• W2004017776 cites W2091972500 @default.
• W2004017776 cites W2095469358 @default.
• W2004017776 cites W2100429960 @default.
• W2004017776 cites W2102579789 @default.
• W2004017776 cites W2105324548 @default.
• W2004017776 cites W2107025480 @default.
• W2004017776 cites W2124523054 @default.
• W2004017776 cites W2125037934 @default.
• W2004017776 cites W2133416961 @default.
• W2004017776 cites W2134026606 @default.
• W2004017776 cites W2135960212 @default.
• W2004017776 cites W2142244352 @default.
• W2004017776 cites W2151003442 @default.
• W2004017776 cites W2151954645 @default.
• W2004017776 cites W2156328797 @default.
• W2004017776 cites W2158221767 @default.
• W2004017776 cites W2160776726 @default.
• W2004017776 cites W2165896332 @default.

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