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• W2004037916 abstract "Abstract A series of stable silylene–transition metal complexes have been synthesized by substitution of silylenes 1 and 2 for carbonyl ligands in simple metal carbonyl complexes: M(1)2(CO)4 and M(2)2(CO)4 (M=Cr, Mo, W), Fe(1)(CO)4 and Ru(1)2(CO)3. X-ray crystal structures are reported. Infrared and NMR spectroscopy were used to probe the electronic properties of stable silylene ligands. Based on these data, the stable silylene 1 behaves electronically very much like triaryl phosphines." @default.
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• W2004037916 date "2001-11-01" @default.
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• W2004037916 title "Electronic and steric properties of stable silylene ligands in metal(0) carbonyl complexes" @default.
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• W2004037916 doi "https://doi.org/10.1016/s0022-328x(01)00765-3" @default.
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