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- W2004053845 abstract "Spherically averaged electron-pair relative-motion (intracule) densities $h(u)$ in position space and $overline{h}(v)$ in momentum space represent probability densities of finding interelectronic position and momentum distances, $|{mathbf{r}}_{j}ensuremath{-}{mathbf{r}}_{k}|$ and $|{mathbf{p}}_{j}ensuremath{-}{mathbf{p}}_{k}|,$ of any pair of electrons $j$ and $k$ to be $u$ and $v,$ respectively. Using the numerical Hartree-Fock method, these electron-pair densities $h(u)$ and $overline{h}(v)$ are constructed and examined systematically for the atoms from He to Xe in their ground state. In position space, the intracule density $h(u)$ is a monotonically decreasing function for all the atoms. In momentum space, however, the intracule densities $overline{h}(v)$ are found to be classified into three types according to the number of local maxima and their locations. These different behaviors of the densities $h(u)$ and $overline{h}(v)$ are studied in detail based on the contributions of electrons in a pair of atomic spinorbitals and subshells." @default.
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- W2004053845 date "1998-03-01" @default.
- W2004053845 modified "2023-10-18" @default.
- W2004053845 title "Electron-pair relative-motion densities of atoms in position and momentum spaces" @default.
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- W2004053845 doi "https://doi.org/10.1103/physreva.57.1759" @default.
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