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• W2004059420 endingPage "1363" @default.
• W2004059420 startingPage "1360" @default.
• W2004059420 abstract "Relative orientations of the DNA strands within a purine⋅purine⋅pyrimidine triple helix have been determined by affinity cleaving. A purine-rich oligonucleotide bound in the major groove of double-helical DNA antiparallel to the Watson-Crick purine strand. Binding depended upon the concentration of multivalent cations such as spermine or Mg2+, and appeared to be relatively independent of pH. Two models with specific hydrogen-bonding patterns for base triplets (G⋅GC, A⋅AT, and T⋅AT) are proposed to explain the sequence specificity of binding. The two models differ in the conformation about the glycosyl bond (syn or anti) and the location of the phosphate-deoxyribose backbone in the major groove of DNA. This motif broadens the structural frameworks available as a basis for the design of sequence-specific DNA binding molecules." @default.
• W2004059420 created "2016-06-24" @default.
• W2004059420 creator A5064820122 @default.
• W2004059420 creator A5076578241 @default.
• W2004059420 date "1991-03-15" @default.
• W2004059420 modified "2023-10-06" @default.
• W2004059420 title "Second Structural Motif for Recognition of DNA by Oligonucleotide-Directed Triple-Helix Formation" @default.
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• W2004059420 doi "https://doi.org/10.1126/science.2003222" @default.
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