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• W2004064420 abstract "The electrochemical polymerisation of Co(L)3(BF4)2 (where L = 4-methyl,4′(2.pyrrol-1-ylethyl)-2,2′-bipyridine) on a gold electrode has been performed in CH3CN + tetraethylammonium perchlorate solution. The properties of the film have been examined by means of voltammetric techniques and compared to those of Co(L)3(BF4) and Co(Bipy)3(BF4)2 in solution. The redox potentials of the three systems on the modified electrode are: Co(III)/Co(II), E°′ = 0.240 V; Co(II)/Co(I), E°′ = −1.090 V and Co(I)/Co(−I), E°′ = −1.80 V. The systems appear to be quasi-reversible and are similar to those observed with the corresponding Co(L)3(BF4)2 complex in solution. The variations of the redox potentials of the polymer vs. the concentration of ligands (Bipy, acrylonitrile, allyl chloride) in solution show that exchange between L linked to the polypyrrole matrix and ligands can be observed inside the polymeric film. This property allows the film to be used in the catalytic reduction of allyl chloride at −1.2 V." @default.
• W2004064420 created "2016-06-24" @default.
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• W2004064420 date "1987-06-01" @default.
• W2004064420 modified "2023-10-18" @default.
• W2004064420 title "Redox and electrocatalytic properties of cobalt-bipyridyl-polypyrrole film electrodes" @default.
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• W2004064420 doi "https://doi.org/10.1016/0022-0728(87)85086-6" @default.
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