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- W2004077983 abstract "The self-assembly mechanism of alkanethiol monolayers on the (111) surface of gold was discovered with the use of an ultrahigh-vacuum scanning tunneling microscope. Monolayer formation follows a two-step process that begins with condensation of low-density crystalline islands, characterized by surface-aligned molecular axes, from a lower density lattice-gas phase. At saturation coverage of this phase, the monolayer undergoes a phase transition to a denser phase by realignment of the molecular axes with the surface normal. These studies reveal the important role of molecule-substrate and molecule-molecule interactions in the self-assembly of these technologically important material systems." @default.
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- W2004077983 date "1996-05-24" @default.
- W2004077983 modified "2023-10-16" @default.
- W2004077983 title "The Self-Assembly Mechanism of Alkanethiols on Au(111)" @default.
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- W2004077983 doi "https://doi.org/10.1126/science.272.5265.1145" @default.
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