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- W2004080649 abstract "The authors previously developed a rapid and inexpensive procedure to fractionate free fatty acid (FFA) mixtures via urea complex UC formation. The process yields two phases in equilibrium, a solvent-rich extract phase containing unsaturated FFA and a solid raffinate phase consisting of UCs of saturated and monounsaturated FFA. It effectively removed saturated FFA, that is, palmitic and stearic acid, from an FFA mixture derived from low erucic acid rapeseed (LEAR) oil. In the present study, triangular phase diagrams were determined for the urea/ethanol/water/LEAR-FFA system at various temperatures, which delineated the phase boundary between the 1-phase and 2-phase regions. Calculations of the amounts and distribution of urea and LEAR-FFA between the two phases based on tie-lines from the phase diagram strongly agreed with experimental data. The diagram accurately predicted the temperature required to cosolubilize urea and LEAR-FFA in solvent. A plot of the percent extraction of an individual FFA species ..." @default.
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- W2004080649 date "2001-02-13" @default.
- W2004080649 modified "2023-09-30" @default.
- W2004080649 title "TRIANGULAR PHASE DIAGRAMS TO PREDICT THE FRACTIONATION OF FREE FATTY ACID MIXTURES VIA UREA COMPLEX FORMATION" @default.
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- W2004080649 doi "https://doi.org/10.1081/ss-100000850" @default.
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