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- W2004080777 abstract "We describe the first total synthesis and structural determination of akaterpin, an inhibitor of phosphatidylinositol-specific phospholipase C (PI-PLC). The key features of the synthetic strategy include a regio- and stereoselective C-alkylation at the angular C1′ position and an exo-selective intermolecular Diels–Alder reaction. The relative stereochemistry was determined by a comparison of the NMR spectra of synthetic akaterpin with those of natural akaterpin." @default.
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- W2004080777 date "2011-09-01" @default.
- W2004080777 modified "2023-10-14" @default.
- W2004080777 title "Synthesis and determination of the relative structure of akaterpin, a potent inhibitor of PI-PLC" @default.
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- W2004080777 doi "https://doi.org/10.1016/j.tetlet.2011.07.079" @default.
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