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• W2004084145 abstract "Reactions of the disulfides Ph2S2 and (CO)6Fe2s2 with (MeCN)3Mo(CO)3 (I) leading to the splitting of SS bonds have been studied. Binuclear (MeCN)2(CO)6Mo2(μ-SPh)2 (II) is obtained from the reaction of I with Ph2S2. The X-ray diffraction data for II (space group P21, a 9.262(4), b 9.343(10), c 15.494(6), β 105.85(3), Z = 2, R = 0.037) show the MoMo bond of length (2.982(1) Å), to be supported by thiolate bridges (MoS 2.468(1) Å). Interaction of I with the ferrosulfide dimer breaks the SS and FeFe bonds to give an antiferromagnetic nonanuclear cluster Mo2Fe7S8(CO)22 (III) (μeff 2.61(298 K) − 1.92(78 K) BM). An X-ray diffraction study (space group P1, a 13.003(2), b 14.278(1), c 16.019(2) Å, α = 109.555(8), β 97.187(10), γ 113.006(7)°, Z = 2, R = 0.045) has revealed that molecule III consists of two fragments (CO)9Fe3(S)4Mo(CO)2 (MoFe 2.750(2) Å, FeS 2.260(3) Å, MoS 2.406(3) Å) linked via the Fe atom (MoFe 2.900(2) Å, FeS 2.242(3) and 2.529(3) Å), but without FeFe bonds." @default.
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• W2004084145 date "1989-04-01" @default.
• W2004084145 modified "2023-10-14" @default.
• W2004084145 title "Formation of clusters by oxidative addition of organic and inorganic disulfides. Molecular structures of (Me(CN)2(CO)6Mo2(μ-SPh)2 and Mo2Fe7S8(CO)22" @default.
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• W2004084145 doi "https://doi.org/10.1016/0022-328x(89)87028-7" @default.
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