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- W2004094088 abstract "1. The effect of a mercurial on circular dichroism (CD) of B-phycoerythrin, R-phycoerythrin and C-phycocyanin has been investigated. 2. B-phycoerythrin exhibits a double CD band centered at the longest wavelength absorption. Upon treatment with a mercurial, the double CD band appears to reverse its sign resulting in a different double CD band shifted toward shorter wavelengths. 3. R-phycoerythrin, having three positive CD bands, lacks the double CD band both before and after mercurial treatment. 4. C-phycocyanin from Anacystis nidulans shows two positive CD bands. The longer wavelength CD band at pH 5 is much greater than the shorter wavelength band. At pH 7, where both bands are of about the same intensity and are well separated, the longer wavelength CD band shifts to a shorter wavelength in the presence of a mercurial. 5. Subsequent addition of mercaptoethanol brings about a partial regeneration of the longest wavelength positive CD band in the case of both R-phycoerythrin and C-phycocyanin but not with mercurial-treated B-phycoerythrin which produces a double CD band of opposite sign. 6. These CD changes are discussed in connection with absorption spectral changes as well as with the dissociation and association aspects of these chromoproteins." @default.
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- W2004094088 date "1969-09-01" @default.
- W2004094088 modified "2023-09-25" @default.
- W2004094088 title "Mercurial-induced circular dichroism changes of phycoerythrin and phycocyanin" @default.
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- W2004094088 doi "https://doi.org/10.1016/0005-2795(69)90070-1" @default.
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