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- W2004099897 abstract "The thermotropic liquid crystalline behaviour of two N-alkylpyridinium tetrahalocuprates was investigated. The n-pentadecyl tetrachloro and tetrabromo derivatives (CU15-CL and CU15-BR, respectively) exhibit very similar behaviour on cooling, and specifically, a high temperature smectic phase followed by a cubic phase. We fully elucidated the Ia3¯d space group for the cubic phase from X-ray diffraction on single crystals. The type of cubic phase is still under discussion, but we suggest that it is a direct type of structure based on the known phase sequence of lower and higher homologues. A model for the local organization of CU15-CL and CU15-BR in the cubic and smectic mesophases is also proposed." @default.
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- W2004099897 date "2004-07-01" @default.
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- W2004099897 title "An<i>Ia</i>3¯<i>d</i>thermotropic cubic phase from<i>N</i>-alkylpyridinium tetrahalocuprates" @default.
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- W2004099897 doi "https://doi.org/10.1080/02678290410001713351" @default.
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