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- W2004102593 abstract "Pressure–temperature–volume (PVT) data have been obtained for poly(propylene glycol) of molecular weight 1025 containing LiCF3SO3 in the mole ratio 20:1. The PVT data were used to calculate the specific volumes, V/VP=0,T=296 K, associated with the pressures and temperatures for previously published variable temperature, high-pressure electrical conductivity data. It is found that the electrical conductivity depends strongly on temperature at a constant volume. Consequently, traditional free volume theory is not consistent with the data. Finally, it is shown that the features of the electrical conductivity data can be accounted for by a recently developed generalized Vogel theory." @default.
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- W2004102593 date "2003-06-01" @default.
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- W2004102593 title "The need to reconsider traditional free volume theory for polymer electrolytes" @default.
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- W2004102593 doi "https://doi.org/10.1016/s0013-4686(03)00213-5" @default.
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