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- W2004102947 abstract "Abstract The structure and magnetocaloric properties of Tb substituted Gd 3 Ga 5 O 12 garnets have been investigated. The structural refinement of X-ray diffraction patterns show that Gd 3− x Tb x Ga 5 O 12 ( x =0, 1, 2, 3) are isostructural, with the symmetry of a cubic space group Ia 3 ¯ d . The temperature dependence of magnetization studies indicate that all the samples follow Curie–Weiss paramagnetic behavior above 25 K and the effective magnetic moment increases with Tb concentration. The low temperature magnetization studies suggest that there exists a field dependent antiferromagnetic ordering of rare earth ions in Tb substituted Gd 3 Ga 5 O 12 , which in turn leads to a lower magnetic moment in Gd 3− x Tb x Ga 5 O 12 ( x =1, 2, 3), compared to that of Gd 3 Ga 5 O 12 . Magnitude of field corresponding to the antiferromagnetic ordering is found to be dependent on temperature as well as on Tb concentration. Magnetocaloric effect analysis confirms that Tb substitution enhances the magnetic entropy change at higher temperatures and Gd 3− x Tb x Ga 5 O 12 ( x =1, 2, 3) are better candidates than Gd 3 Ga 5 O 12 for low fields and low temperature magnetic refrigeration applications." @default.
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- W2004102947 date "2012-06-01" @default.
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- W2004102947 title "Magnetic and magnetocaloric properties of Gd3−xTbxGa5O12 (x=0, 1, 2, 3) garnets" @default.
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- W2004102947 doi "https://doi.org/10.1016/j.jmmm.2012.01.030" @default.
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