FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004125971> ?p ?o ?g. }

• W2004125971 endingPage "1742" @default.
• W2004125971 startingPage "1735" @default.
• W2004125971 abstract "Standard potentials of I3−/I− and I2/I3− redox couples relative to that of aqueous saturated calomel reference electrode SCE (W), ESCE(w) have been determined in propylene carbonate (PC), N,N-dimethylformamide (DMF), acetonitrile (ACN), and their binary mixtures at 25 °C from potentiometric measurements. The results helped evaluate the standard potentials of the redox couple I2/I− relative to ESCE(w) as well as the related formation constant (Kf) of I3− in these solvent systems. The solvent effects on the formation equilibrium I2+I−ightleftharpoonsI3− were analyzed in the light of the transfer free energies of I2, ΔGt°(I2), as obtained from solubility measurements of I2 in the solvents, that of I−, ΔGt°(I−), as obtained earlier by use of the widely used TATB reference electrolyte assumption and that of I3−, ΔGt°(I3−), as obtained by subtracting these two contributions from the respective transfer free energies of formation equilibrium in the mixed solvents relative to a chosen reference solvent in each solvent system. The solvation behavior of these individual iodine species viz. I2, I−, I3− was interpreted in terms of involved interaction viz. Born, ion-dipole, ion-induced dipole, dispersion type soft–soft interactions, CTTS complexation and also the cavity effect as computed by the scaled particle theory (SPT)." @default.
• W2004125971 created "2016-06-24" @default.
• W2004125971 creator A5020773345 @default.
• W2004125971 creator A5029783733 @default.
• W2004125971 creator A5082034007 @default.
• W2004125971 date "1988-05-01" @default.
• W2004125971 modified "2023-09-24" @default.
• W2004125971 title "Relative Standard Electrode Potentials of I₃⁻/I⁻, I₂/I₃⁻, and I₂/I⁻Redox Couples and the Related Formation Constants of I₃⁻in Some Pure and Mixed Dipolar Aprotic Solvents" @default.
• W2004125971 cites W1522473361 @default.
• W2004125971 cites W1970048630 @default.
• W2004125971 cites W1975160614 @default.
• W2004125971 cites W1984096090 @default.
• W2004125971 cites W2005364880 @default.
• W2004125971 cites W2005877813 @default.
• W2004125971 cites W2023211798 @default.
• W2004125971 cites W2045119560 @default.
• W2004125971 cites W2083838718 @default.
• W2004125971 cites W2091653555 @default.
• W2004125971 cites W2092154262 @default.
• W2004125971 cites W2101185742 @default.
• W2004125971 cites W2170007401 @default.
• W2004125971 cites W2313147062 @default.
• W2004125971 cites W2314391847 @default.
• W2004125971 cites W2321694187 @default.
• W2004125971 cites W2327838960 @default.
• W2004125971 cites W2330732210 @default.
• W2004125971 cites W2332917571 @default.
• W2004125971 cites W27727037 @default.
• W2004125971 cites W4234710627 @default.
• W2004125971 cites W2065812042 @default.
• W2004125971 doi "https://doi.org/10.1246/bcsj.61.1735" @default.
• W2004125971 hasPublicationYear "1988" @default.
• W2004125971 type Work @default.
• W2004125971 sameAs 2004125971 @default.
• W2004125971 citedByCount "60" @default.
• W2004125971 countsByYear W20041259712012 @default.
• W2004125971 countsByYear W20041259712014 @default.
• W2004125971 countsByYear W20041259712015 @default.
• W2004125971 countsByYear W20041259712016 @default.
• W2004125971 countsByYear W20041259712017 @default.
• W2004125971 countsByYear W20041259712018 @default.
• W2004125971 countsByYear W20041259712019 @default.
• W2004125971 countsByYear W20041259712020 @default.
• W2004125971 countsByYear W20041259712021 @default.
• W2004125971 countsByYear W20041259712022 @default.
• W2004125971 countsByYear W20041259712023 @default.
• W2004125971 crossrefType "journal-article" @default.
• W2004125971 hasAuthorship W2004125971A5020773345 @default.
• W2004125971 hasAuthorship W2004125971A5029783733 @default.
• W2004125971 hasAuthorship W2004125971A5082034007 @default.
• W2004125971 hasBestOaLocation W20041259711 @default.
• W2004125971 hasConcept C113196181 @default.
• W2004125971 hasConcept C124614425 @default.
• W2004125971 hasConcept C145148216 @default.
• W2004125971 hasConcept C147789679 @default.
• W2004125971 hasConcept C148093993 @default.
• W2004125971 hasConcept C17525397 @default.
• W2004125971 hasConcept C178790620 @default.
• W2004125971 hasConcept C184651966 @default.
• W2004125971 hasConcept C185592680 @default.
• W2004125971 hasConcept C2777463227 @default.
• W2004125971 hasConcept C2777983707 @default.
• W2004125971 hasConcept C2780471494 @default.
• W2004125971 hasConcept C2780709120 @default.
• W2004125971 hasConcept C2911131995 @default.
• W2004125971 hasConcept C68801617 @default.
• W2004125971 hasConcept C96345733 @default.
• W2004125971 hasConceptScore W2004125971C113196181 @default.
• W2004125971 hasConceptScore W2004125971C124614425 @default.
• W2004125971 hasConceptScore W2004125971C145148216 @default.
• W2004125971 hasConceptScore W2004125971C147789679 @default.
• W2004125971 hasConceptScore W2004125971C148093993 @default.
• W2004125971 hasConceptScore W2004125971C17525397 @default.
• W2004125971 hasConceptScore W2004125971C178790620 @default.
• W2004125971 hasConceptScore W2004125971C184651966 @default.
• W2004125971 hasConceptScore W2004125971C185592680 @default.
• W2004125971 hasConceptScore W2004125971C2777463227 @default.
• W2004125971 hasConceptScore W2004125971C2777983707 @default.
• W2004125971 hasConceptScore W2004125971C2780471494 @default.
• W2004125971 hasConceptScore W2004125971C2780709120 @default.
• W2004125971 hasConceptScore W2004125971C2911131995 @default.
• W2004125971 hasConceptScore W2004125971C68801617 @default.
• W2004125971 hasConceptScore W2004125971C96345733 @default.
• W2004125971 hasIssue "5" @default.
• W2004125971 hasLocation W20041259711 @default.
• W2004125971 hasOpenAccess W2004125971 @default.
• W2004125971 hasPrimaryLocation W20041259711 @default.
• W2004125971 hasRelatedWork W1967885954 @default.
• W2004125971 hasRelatedWork W1972141970 @default.
• W2004125971 hasRelatedWork W2024477039 @default.
• W2004125971 hasRelatedWork W2028028162 @default.
• W2004125971 hasRelatedWork W2035155725 @default.
• W2004125971 hasRelatedWork W2037091577 @default.
• W2004125971 hasRelatedWork W2040908237 @default.
• W2004125971 hasRelatedWork W2047613345 @default.
• W2004125971 hasRelatedWork W2329261274 @default.
• W2004125971 hasRelatedWork W2951314393 @default.
• W2004125971 hasVolume "61" @default.

• next