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• W2004127722 abstract "A water stable porous 3D metal-organic framework, [Cu3L2(μ3-OH)2(μ2-H2O)]·2DMA (1, mother crystal, H2L = 2,2'-dinitrobiphenyl-4,4'-dicarboxylic acid, DMA = N,N-dimethylacetamide), shows unprecedented irreversible solvent-induced substitutions of bridging aqua ligands and guest-exchanges in single-crystal-to-single-crystal (SCSC) transformations at room temperature (RT), producing quantitatively three daughter crystals, [Cu3L2(μ3-OH)2]·2S (2: 2A, S = acetone; 2B, S = 2-propanol; 2C, S = 2-butanol), which exhibit reversible interconversion by guest-exchanges at RT in SCSC transformations. MOF 1 shows excellent separation selectivity (128) of CO2/N2 at RT and is a better sorbent of micro-solid-phase extraction (μ-SPE) than currently known benchmark ZIF-8." @default.
• W2004127722 created "2016-06-24" @default.
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• W2004127722 date "2014-01-01" @default.
• W2004127722 modified "2023-10-06" @default.
• W2004127722 title "A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO₂ adsorption selectivity at room temperature" @default.
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• W2004127722 doi "https://doi.org/10.1039/c4cc06588c" @default.
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