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- W2004129969 abstract "2,2'-Diaminodiphenyldisulphide is a highly sensitive platinum chromogen. Platinum(IV) forms a complex with it in 50% aqueous ethanol at pH 5.0-6.0, having maximum absorption at 725 nm. The molar absorptivity of the complex is 5.48 x 10(4)1.mole(-1).cm(-1) at 725nm and the sensitivity is 0.0035 mug/cm(2). The colour system obeys Beer's law from 0.25 to 5 ppm with optimum concentration range 0.75-4 ppm of platinum. The relative error is 2.7%. The metal to reagent ratio is 1:2, and the stepwise formation constants K(1) and K(2) are 5.6 x 10(4) and 1.96 x 10(4) respectively." @default.
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- W2004129969 date "1977-02-01" @default.
- W2004129969 modified "2023-09-26" @default.
- W2004129969 title "2,2′-Diaminodiphenyldisulphide—a new sensitive spectrophotometric reagent for platinum" @default.
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- W2004129969 doi "https://doi.org/10.1016/0039-9140(77)80164-1" @default.
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