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• W2004134759 abstract "In situ immobilization of heavy metals in polluted soils using phosphates leads to formation of products which are highly insoluble and thermodynamically stable over a broad pH and Eh range. In this research effectivity of Cd ions immobilization (initial [Cdaq]-4.800 mM) from aqueous solutions by different phosphorus compounds (K2HPO4, NH4H2PO4 and Polifoska 15 fertilizer) was compared at pH in the range 4.00-9.00 and for reaction times 2-1440 h. The highest reduction of cadmium concentration (>99%), owing due to the formation of cadmium phosphates, was observed for all used phosphorus sources within pH range of 6.75-9.00. Uptake of cadmium for pH< or =5.00 did not exceed 80% and was lowest in the reaction with Polifoska 15 fertilizer (28.25%). Identification of phases formed in the reactions using XRD, FTIR and SEM-EDS-EBSD was carried out. It was noticed that crystallinity of formed solid decreased with pH increase. Formation of Cd5H2(PO4)4.4H2O was observed in acidic conditions (pH< or =5.00), at pH approximately 7.00 mixture of following cadmium phosphates Cd(H2PO4)2, Cd3(PO4)2 and Cd5H2(PO4)4.4H2O was formed. Amorphic cadmium phosphates were noticed in alkaline conditions (pH>8.50)." @default.
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• W2004134759 date "2008-04-01" @default.
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• W2004134759 title "Immobilization of aqueous cadmium by addition of phosphates" @default.
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• W2004134759 doi "https://doi.org/10.1016/j.jhazmat.2007.08.010" @default.
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