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- W2004136712 abstract "Inosine-5′-monophosphate disodium salt (5′-IMPNa 2 ) reacts with cis-dichlorodiammineplatinum(II) (cis-DDP) and its trans-isomer (trans-DDP) to give complexes of the type cis- and trans-Pt(NH 3 ) 2 (IMPNa 2 )nCl 2• xH 2 O, n = 1 or 2 and Pt(IMPNa 2 ) n Cl 2• xH 2 O, where n = 1, 2, or 3 and x = 0–6. In the 1:2 platinum complexes the nucleotide binds only to the N 7 -atom of the purine ring system, while in the 1:1 metal complexes there is indication for Pt–carbonyl interaction (bridging or chelation) in addition to the N 7 -bonding at neutral pH values with cis-DDP.Solution FT-ir studies (H 2 O and D 2 O) showed that the 1:1 species formed with cis-DDP at neutral pH's behaved differently from those with trans-DDP. The carbonyl stretching vibration of the free base at 1685 cm −1 (H 2 O) and 1670 cm −1 (D 2 O) exhibited marked spectral changes in intensity, shifting, and shape upon complexation, whereas the reaction with the trans-isomer produced only slight perturbations in the above region." @default.
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- W2004136712 date "1984-08-01" @default.
- W2004136712 modified "2023-09-26" @default.
- W2004136712 title "An FT-ir study of cis study of trans-dichlorodiammineplatinum(II) bound to inosine-5′-monophosphate" @default.
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- W2004136712 doi "https://doi.org/10.1139/v84-242" @default.
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