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- W2004137795 abstract "Abstract A library of chiral zinc complexes formed in situ by the combination of achiral and racemic diimines with 3,3′-di(3,5-ditrifluoromethylphenyl)-BINOL and diethylzinc were evaluated in the asymmetric addition of diethylzinc to N-acylimines. In the presence of 10 mol % of chiral ligand 4 and racemic diimine 5, high enantioselectivities of up to 97% ee and yields of up to 96% were achieved for a wide range of aromatic imines in dichloromethane at −30 °C." @default.
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- W2004137795 date "2005-09-01" @default.
- W2004137795 modified "2023-09-23" @default.
- W2004137795 title "Discovery of chiral catalysts by asymmetric activation for highly enantioselective diethylzinc addition to imines: using racemic and achiral diimines as effective activators" @default.
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- W2004137795 doi "https://doi.org/10.1016/j.tetasy.2005.07.014" @default.
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