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- W2004143465 abstract "Abstract A new oxide‐centered trinuclear manganese(III) compound with the formula [Mn 3 (μ 3 ‐O)(naphpz) 3 (O 2 CMe)(MeOH) 2 ] n ( 1 ) {H 2 naphpz = 2‐[1 H ‐pyrazol‐5(3)‐yl]naphthalen‐1‐ol} has been synthesized and characterized. Three bulky doubly deprotonated phenol‐pyrazole ligands are coordinated to the three manganese(III) ions with a μ 3 ‐oxide bridge in the same plane. Methanol and acetate ligands are at the apical positions of the manganese(III) ions. The trinuclear units are bridged by acetate ligands in the anti‐anti mode, leading to the formation of 1‐D chains. Temperature‐dependent magnetic susceptibility studies indicate the presence of overall antiferromagnetic interactions with magnetic exchange constants of J 1 ≈ –1.9 and J 2 ≈ –5.5 cm –1 and g = 1.91. Weak antiferromagnetic interactions ( zJ′ = –0.37 cm –1 ) between the trinuclear units in the 1‐D chain (and between the chains) in compound 1 are present." @default.
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- W2004143465 date "2010-02-01" @default.
- W2004143465 modified "2023-10-13" @default.
- W2004143465 title "An Oxide‐Centered Trinuclear Manganese(III) Compound with a Bulky Phenol‐Pyrazolate Ligand" @default.
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- W2004143465 doi "https://doi.org/10.1002/ejic.200901007" @default.
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