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• W2004153105 abstract "Copolymers of poly(silphenylene–siloxane) with dimethylsiloxane and diphenylsiloxane with various end groups were synthesized through an SiH/SiOR polycondensation process. The thermooxidative degradation behaviors of the copolymers were investigated by thermogravimetric analysis and IR spectrometry techniques. All of the polymers were characterized by a two-step mass loss. The first one, which peaked at 510–545°C in differential thermogravimetric curves, was mostly caused by the main-chain depolymerization, whereas the second one, which reached its maximum around 650°C, was caused by side-group oxidation and SiC bond scission. The main-chain depolymerization occurred over a temperature range of some 470–580°C, whereas SiC bond scission and side-group oxidation occurred over a temperature range of about 585°C to above 720°C. The incorporation of phenyl groups in the end groups greatly retarded the temperature for the degradation onset of the main chain to 120°C higher. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010" @default.
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• W2004153105 date "2010-07-15" @default.
• W2004153105 modified "2023-10-12" @default.
• W2004153105 title "Thermooxidative degradation behavior of poly(silphenylene-siloxane)s" @default.
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• W2004153105 doi "https://doi.org/10.1002/app.31429" @default.
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