Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004155326> ?p ?o ?g. }
- W2004155326 endingPage "6758" @default.
- W2004155326 startingPage "6753" @default.
- W2004155326 abstract "Thiamine is presently one of the most attractive substrates used for sensitive fluorometric measurements of peroxides. Thiochrome (TC), a highly fluorescent product, is formed in enzyme-mediated oxidations. It is assumed that H2O2 is nearly quantitatively converted to TC. The reaction cannot differentiate H2O2 from many other peroxides such as methylhydroperoxide (MHP); to perform differential measurements, H2O2 can first be selectively destroyed by a suitable catalyst such as MnO2. In substituting Ag2O for MnO2 to accomplish the selective destruction of H2O2, we achieved the stated objective but were puzzled by a 3-fold increase in the MHP response in the presence of Ag2O. It was soon discovered that traces of dissolved Ag+ and Hg2+ can dramatically increase the yield of TC in this reaction from either H2O2 or MHP; the normal yield in fact is only 20%. We present here a reaction scheme and kinetic model that adequately describes this behavior and should provide a path to substantially increase the sensitivity of this important assay method." @default.
- W2004155326 created "2016-06-24" @default.
- W2004155326 creator A5043815322 @default.
- W2004155326 creator A5045932804 @default.
- W2004155326 creator A5046170578 @default.
- W2004155326 creator A5058356398 @default.
- W2004155326 date "2003-10-29" @default.
- W2004155326 modified "2023-09-25" @default.
- W2004155326 title "Silver-Induced Enhancement of Thiochrome-Based Peroxide Measurements" @default.
- W2004155326 cites W121021299 @default.
- W2004155326 cites W1967754931 @default.
- W2004155326 cites W1968578385 @default.
- W2004155326 cites W1971725258 @default.
- W2004155326 cites W1978231584 @default.
- W2004155326 cites W1978292741 @default.
- W2004155326 cites W1978957493 @default.
- W2004155326 cites W1983340520 @default.
- W2004155326 cites W1984435519 @default.
- W2004155326 cites W1987608377 @default.
- W2004155326 cites W1993467288 @default.
- W2004155326 cites W2003487925 @default.
- W2004155326 cites W2003947645 @default.
- W2004155326 cites W2026124364 @default.
- W2004155326 cites W2029475776 @default.
- W2004155326 cites W2032561557 @default.
- W2004155326 cites W2034732327 @default.
- W2004155326 cites W2039123718 @default.
- W2004155326 cites W2056682549 @default.
- W2004155326 cites W2058730595 @default.
- W2004155326 cites W2060039677 @default.
- W2004155326 cites W2063333966 @default.
- W2004155326 cites W2072590806 @default.
- W2004155326 cites W2078823058 @default.
- W2004155326 cites W2080495236 @default.
- W2004155326 cites W2093296914 @default.
- W2004155326 cites W2094336289 @default.
- W2004155326 cites W2159876508 @default.
- W2004155326 cites W2263428899 @default.
- W2004155326 cites W2418991793 @default.
- W2004155326 doi "https://doi.org/10.1021/ac0349126" @default.
- W2004155326 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14640758" @default.
- W2004155326 hasPublicationYear "2003" @default.
- W2004155326 type Work @default.
- W2004155326 sameAs 2004155326 @default.
- W2004155326 citedByCount "12" @default.
- W2004155326 countsByYear W20041553262013 @default.
- W2004155326 countsByYear W20041553262015 @default.
- W2004155326 countsByYear W20041553262019 @default.
- W2004155326 countsByYear W20041553262021 @default.
- W2004155326 crossrefType "journal-article" @default.
- W2004155326 hasAuthorship W2004155326A5043815322 @default.
- W2004155326 hasAuthorship W2004155326A5045932804 @default.
- W2004155326 hasAuthorship W2004155326A5046170578 @default.
- W2004155326 hasAuthorship W2004155326A5058356398 @default.
- W2004155326 hasConcept C121332964 @default.
- W2004155326 hasConcept C134121241 @default.
- W2004155326 hasConcept C135889238 @default.
- W2004155326 hasConcept C161790260 @default.
- W2004155326 hasConcept C178790620 @default.
- W2004155326 hasConcept C185592680 @default.
- W2004155326 hasConcept C21951064 @default.
- W2004155326 hasConcept C2776203871 @default.
- W2004155326 hasConcept C2781048764 @default.
- W2004155326 hasConcept C533411734 @default.
- W2004155326 hasConcept C62520636 @default.
- W2004155326 hasConcept C75473681 @default.
- W2004155326 hasConcept C91881484 @default.
- W2004155326 hasConcept C97355855 @default.
- W2004155326 hasConceptScore W2004155326C121332964 @default.
- W2004155326 hasConceptScore W2004155326C134121241 @default.
- W2004155326 hasConceptScore W2004155326C135889238 @default.
- W2004155326 hasConceptScore W2004155326C161790260 @default.
- W2004155326 hasConceptScore W2004155326C178790620 @default.
- W2004155326 hasConceptScore W2004155326C185592680 @default.
- W2004155326 hasConceptScore W2004155326C21951064 @default.
- W2004155326 hasConceptScore W2004155326C2776203871 @default.
- W2004155326 hasConceptScore W2004155326C2781048764 @default.
- W2004155326 hasConceptScore W2004155326C533411734 @default.
- W2004155326 hasConceptScore W2004155326C62520636 @default.
- W2004155326 hasConceptScore W2004155326C75473681 @default.
- W2004155326 hasConceptScore W2004155326C91881484 @default.
- W2004155326 hasConceptScore W2004155326C97355855 @default.
- W2004155326 hasIssue "23" @default.
- W2004155326 hasLocation W20041553261 @default.
- W2004155326 hasLocation W20041553262 @default.
- W2004155326 hasOpenAccess W2004155326 @default.
- W2004155326 hasPrimaryLocation W20041553261 @default.
- W2004155326 hasRelatedWork W2001542384 @default.
- W2004155326 hasRelatedWork W2066236574 @default.
- W2004155326 hasRelatedWork W2084566861 @default.
- W2004155326 hasRelatedWork W2112223020 @default.
- W2004155326 hasRelatedWork W2124188121 @default.
- W2004155326 hasRelatedWork W2365702689 @default.
- W2004155326 hasRelatedWork W2367302301 @default.
- W2004155326 hasRelatedWork W2463202479 @default.
- W2004155326 hasRelatedWork W2950980354 @default.
- W2004155326 hasRelatedWork W3002660080 @default.
- W2004155326 hasVolume "75" @default.