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- W2004156064 abstract "Abstract To evaluate the effects of coexisting cations on Cl- adsorption in variable-charge soils, we measured the Cl- adsorption from CaCl2 and MgCl2 solutions on two Andisols as a function of the pH and electrolyte concentration, and compared the results with the adsorption from NH4Cl and NaCl solutions. For the Choyo B soil in which allophane and imogolite are the dominant exchangers, the Cl- adsorption from NaCl, NH4Cl, and MgCl2 solutions was only determined by the pH+pCl values of the bathing solutions. In the CaCl2 solutions, however, the Cl- adsorption deviated positively from the relationship obtained in using the NaCl, NH4Cl, and MgCl2 solutions. We considered that this deviation reflected the CaCl+ ion-pair adsorption on negatively charged sites. In a 50 mmol l-1 CaCl2 solution at pH = 7.1, the estimated CaCl+ ion-pair adsorption amounted up to about 10% of the adsorbed Ca2+ and 56% of the adsorbed Cl- on a mol kg-1 basis. In the lower pH range (< 6.5), however, the CaCl+ adsorption was negligible. Daikanbo A soil whose exchanger consisted of Al-humus complexes showed a net negative adsorption of Cl-. These results suggest that the contribution of MCl+ (M = Ca or Mg) complexes was not significant. The exclusion volume was relatively constant irrespective of the pH and electrolyte concentration. We attributed these results to the Donnan effect." @default.
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- W2004156064 date "1993-12-01" @default.
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- W2004156064 title "CI-adsorption on andisols from CaCl2and MgCl2solutions" @default.
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- W2004156064 doi "https://doi.org/10.1080/00380768.1993.10419181" @default.
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