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• W2004162316 endingPage "155" @default.
• W2004162316 startingPage "149" @default.
• W2004162316 abstract "The complex (pip)2M(CO)4 (pip=C5H10NH; MCr, Mo or W) reacted with nBuLi and CS2 in the presence of Et4NBr to give [Et4N][(C5H10NCS2)M(CO)4](MCr (1), Mo (2), W (3)) in high yield. The reaction is initiated by the abstraction of the NH proton of the piperidine ligand by nBuLi, followed by insertion of CS2 into the MN bond to give the dithiocarbamate metal complexes. The complex [Et4N][(C4H8NCS2)W(CO)4] (4) was similarly prepared. Complexes 1–4 were characterized by elemental analysis and IR, mass and NMR spectroscopy. In addition, the molecular structures of 3 and 4 were determined by single-crystal X-ray diffraction analysis, which confirmed the dihapticity of the dithiocarbamte ligands in 3 and 4. Compound 3 is monoclinic, space group P21, with a = 9.964(2) Å, b = 12.724(1) Å, c = 10.268(3) Å, β = 117.12(2)° and Z = 2. Compound 4 is orthorhombic, space group Pna21, with a = 31.424(5) Å, b = 8.281(1) Å, c = 17.137(2) Å and Z = 8. The structure was refined to the final conventional R of 0.029 and RW of 0.020. The HMBC (1H-detected heteronuclear multiple bond correlation) technique was used to assign the 13C chemical shift of the CS2, group of the dithiocarbamate ligand." @default.
• W2004162316 created "2016-06-24" @default.
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• W2004162316 date "1995-05-01" @default.
• W2004162316 modified "2023-09-23" @default.
• W2004162316 title "New syntheses of [Et4N][(C5H10 NCS2)M(CO)4] (M Cr, Mo and W) Insertion reaction of carbon disulfide into the metal-nitrogen bond" @default.
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• W2004162316 doi "https://doi.org/10.1016/0022-328x(94)05379-p" @default.
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