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• W2004165674 abstract "A vanadyl complex with perfluorinate phthalocyanine, VOPcF16, was prepared. The monomer-dimer solvent dependence was confirmed based on the solvent effect for the Q-band position-that is, VOPcF16 exists as a monomer in a nonpolar solvent such as benzene, but dimerizes in a polar solvent such as acetone. Electron spin resonance data also supported the solvent dependence found. In addition, the substituent effect of fluorine atoms on the redox properties was investigated by measuring the cyclic voltammograms in dichloromethane. On the reduction side, three redox couples were observed, the first two of which were assigned as being due to the reduction of the phthalocyanine ring (to LUMO), whose potentials are 0.4–0.5 V higher than those of the tetra-t-butyl and octabutoxy derivatives, VOPc(t-Bu)4 and VOPc(O-n-Bu)8." @default.
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• W2004165674 date "1995-03-01" @default.
• W2004165674 modified "2023-10-16" @default.
• W2004165674 title "Spectral and electrochemical properties of vanadyl hexadecafluorophthalocyanine" @default.
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• W2004165674 doi "https://doi.org/10.1016/0020-1693(94)04188-2" @default.
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