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• W2004169991 startingPage "8595" @default.
• W2004169991 abstract "Polymeric nanostructures with high aspect ratios, so-called nanopillars, are of interest for a wide range of applications. However, it remains a challenge to fabricate high-density, polymeric nanopillars using soft lithography when the feature size is decreased to hundreds of nanometers and the structures are close to each other. Here, we investigate the fidelity of replica molding technique to fabricate polymer nanopillar arrays with diameters ranging from 300 nm to 1 mum, and we compare the experimental results to the theoretical prediction to understand the nature of the instability of nanopillars. Nanopillars molded from soft materials, poly(dimethylsiloxane) (PDMS), mainly ground collapse due to the adhesive force when the aspect ratio is above 6, whereas those from stiffer materials, polyurethane and epoxy, collapse laterally at a much higher aspect ratio (>/=12), of which the critical value is dependent on the nanopillar's feature size, spacing, height, and shape. Further, we attempt to restore the collapsed high-aspect-ratio nanopillars using supercritical CO(2) drying." @default.
• W2004169991 created "2016-06-24" @default.
• W2004169991 creator A5037928465 @default.
• W2004169991 creator A5042973046 @default.
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• W2004169991 creator A5087048448 @default.
• W2004169991 date "2006-09-01" @default.
• W2004169991 modified "2023-10-17" @default.
• W2004169991 title "Replica Molding of High-Aspect-Ratio Polymeric Nanopillar Arrays with High Fidelity" @default.
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• W2004169991 doi "https://doi.org/10.1021/la061372+" @default.
• W2004169991 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16981781" @default.
• W2004169991 hasPublicationYear "2006" @default.
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