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- W2004175114 abstract "Platinum-catalyzed exchange reactions between deuterated benzene and the following polycyclic aromatic hydrocarbons have been investigated: diphenyl, ortho-, meta-, and para-terphenyls; naphthalene; phenanthrene; pyrene, and dibenzyl. The rapid exchange of weakly adsorbed species such as diphenyl is consistent with the application of the dissociative π-complex substitution mechanism previously proposed for heavy water exchange. Aromatics which exchange slowly with deuterated benzene or heavy water were found to randomize readily (e.g., naphthalene-naphthalene-α-d). The deuteration rates of slowly exchanging species may be increased by the inclusion of strongly adsorbed reagents such as C2H5OD. The present results suggest that slow exchange is not due to the formation of irreversibly adsorbed poisons produced by a side reaction such as polymerization, but may be readily explained by strong, reversible π-complex adsorption." @default.
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- W2004175114 title "Platinum-catalyzed exchange reactions between normal and deuterated aromatics" @default.
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- W2004175114 doi "https://doi.org/10.1016/s0021-9517(66)80005-2" @default.
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