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- W2004175434 abstract "The thermodynamic properties of system (HCl + NaCl + C6H12O6 + H2O) were studied by e.m.f. measurement in the cells without liquid junction: (A)Pt,H2(p=101.325kPa)|HCl(0.01000mol·kg-1)|AgCl–Ag (B)Pt,H2(p=101.325kPa)|HCl(m),C6H12O6(w),H2O(1-w)|AgCl–Ag (C)Pt,H2(p=101.325kPa)|HCl(mA),NaCl(mB),C6H12O6(w),H2O(1-w)|AgCl–Ag At constant total ionic strength (0.5, 1.0, 1.5, and 2.0) mol · kg−1, from (5 to 45) °C, where mA and mB are the molalities of HCl and NaCl, respectively, and w is the mass fraction of fructose in the mixed solvent, which is w = 0.1 during all the measurements. The standard electrode potential of Ag|AgCl in the pure water and mixed solvent has been determined from cells (A), (B). The activity coefficients lg γA of HCl in the mixed solvent system have been determined from cell (C).The results show that the activity coefficients of HCl in (HCl + NaCl) solutions still obey Harned’s Rule. The standard transfer Gibbs free energies, entropy and enthalpy of HCl have been calculated. The primary, secondary and total medium effect of HCl have been calculated and discussed." @default.
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- W2004175434 date "2004-12-01" @default.
- W2004175434 modified "2023-09-27" @default.
- W2004175434 title "Thermodynamic properties of hydrochloric acid in mixed solvents" @default.
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- W2004175434 doi "https://doi.org/10.1016/j.jct.2004.07.003" @default.
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