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- W2004176989 abstract "Abstract High-quality crystalline MSn 2 (M = Cr and Co) thin films have been successfully fabricated by reactive pulsed laser deposition. The physical and electrochemical properties of the as-deposited thin films have been investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), galvanostatic cycling and cyclic voltammetry (CV). XRD measurement indicates that the as-deposited thin films prepared at 400 °C consisted mainly of MSn 2 (M = Cr and Co) with a small quantity of metal tin. The specific reversible capacities of CrSn 2 and CoSn 2 thin film electrodes are found to be 467 mA h/g and 465 mA h/g, respectively. A mechanism involving an irreversible decomposition of MSn 2 (M = Cr and Co) and a classical alloying process of Sn is proposed. MSn 2 (M = Cr and Co) as the starting anode materials for conversion to the Li–Sn alloy can improve its electrochemical performance with high reversible capacity and good stable cycle." @default.
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- W2004176989 date "2006-07-01" @default.
- W2004176989 modified "2023-10-17" @default.
- W2004176989 title "Electrochemical reactions of lithium with transition metal stannides" @default.
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- W2004176989 doi "https://doi.org/10.1016/j.ssi.2006.07.030" @default.
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