Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004183014> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2004183014 endingPage "1083" @default.
- W2004183014 startingPage "1071" @default.
- W2004183014 abstract "Photolysis of the hypoiodites of steroidal cyclic homoallyl alcohols such as cholesterol and of cyclic alcohols such as 5α-androstan-17β-ol generated in situ in benzene with three molar equivalents each of lead tetraacetate and iodine was found generally to result in the unprecedented formation of corresponding lactol acetates in yields up to 66%. The lactol acetates are readily hydrolysed to lactols in most cases during their isolation and lactols are isolated products. Thus, cholesterol gave 4-oxa-A-homocholest-5-en-3-ol and its acetate in a 53% yield. The products differ considerably from those reported by us after the photolysis of the hypoiodites by using mercury(II) oxide and iodine as the reagents for generating the hypoiodites; they also differ from those in the oxidation of the steroidal alcohols with lead tetraacetate alone. The photolysis of the hypoiodite of 2,2-dimethyl-5β-cholestan-3-ol was found to lead to the formation of an anomalous lactol, 2α-iodomethyl-2β-methyl-4-oxa-A-homo-5α-cholest..." @default.
- W2004183014 created "2016-06-24" @default.
- W2004183014 creator A5033235455 @default.
- W2004183014 creator A5085483165 @default.
- W2004183014 creator A5087589635 @default.
- W2004183014 date "1987-03-01" @default.
- W2004183014 modified "2023-09-27" @default.
- W2004183014 title "The Transformation of Cyclic Alcohols into Cyclic Acetals through a New Oxygen Atom Insertion by Photolysis in the Presence of Lead Tetraacetate and Iodine" @default.
- W2004183014 cites W1968981560 @default.
- W2004183014 cites W1971653663 @default.
- W2004183014 cites W1972996962 @default.
- W2004183014 cites W1999564669 @default.
- W2004183014 cites W2005713377 @default.
- W2004183014 cites W2007953604 @default.
- W2004183014 cites W2012594500 @default.
- W2004183014 cites W2015383040 @default.
- W2004183014 cites W2018473368 @default.
- W2004183014 cites W2023337611 @default.
- W2004183014 cites W2047560828 @default.
- W2004183014 cites W2052248542 @default.
- W2004183014 cites W2059003011 @default.
- W2004183014 cites W2063116899 @default.
- W2004183014 cites W2131144992 @default.
- W2004183014 cites W2312653460 @default.
- W2004183014 cites W2519403431 @default.
- W2004183014 doi "https://doi.org/10.1246/bcsj.60.1071" @default.
- W2004183014 hasPublicationYear "1987" @default.
- W2004183014 type Work @default.
- W2004183014 sameAs 2004183014 @default.
- W2004183014 citedByCount "18" @default.
- W2004183014 crossrefType "journal-article" @default.
- W2004183014 hasAuthorship W2004183014A5033235455 @default.
- W2004183014 hasAuthorship W2004183014A5085483165 @default.
- W2004183014 hasAuthorship W2004183014A5087589635 @default.
- W2004183014 hasBestOaLocation W20041830141 @default.
- W2004183014 hasConcept C104317684 @default.
- W2004183014 hasConcept C114793014 @default.
- W2004183014 hasConcept C127313418 @default.
- W2004183014 hasConcept C149635348 @default.
- W2004183014 hasConcept C155647269 @default.
- W2004183014 hasConcept C178790620 @default.
- W2004183014 hasConcept C185592680 @default.
- W2004183014 hasConcept C204241405 @default.
- W2004183014 hasConcept C2777093003 @default.
- W2004183014 hasConcept C2994492776 @default.
- W2004183014 hasConcept C32909587 @default.
- W2004183014 hasConcept C41008148 @default.
- W2004183014 hasConcept C539932907 @default.
- W2004183014 hasConcept C540031477 @default.
- W2004183014 hasConcept C54582936 @default.
- W2004183014 hasConcept C55493867 @default.
- W2004183014 hasConcept C58312451 @default.
- W2004183014 hasConcept C75473681 @default.
- W2004183014 hasConceptScore W2004183014C104317684 @default.
- W2004183014 hasConceptScore W2004183014C114793014 @default.
- W2004183014 hasConceptScore W2004183014C127313418 @default.
- W2004183014 hasConceptScore W2004183014C149635348 @default.
- W2004183014 hasConceptScore W2004183014C155647269 @default.
- W2004183014 hasConceptScore W2004183014C178790620 @default.
- W2004183014 hasConceptScore W2004183014C185592680 @default.
- W2004183014 hasConceptScore W2004183014C204241405 @default.
- W2004183014 hasConceptScore W2004183014C2777093003 @default.
- W2004183014 hasConceptScore W2004183014C2994492776 @default.
- W2004183014 hasConceptScore W2004183014C32909587 @default.
- W2004183014 hasConceptScore W2004183014C41008148 @default.
- W2004183014 hasConceptScore W2004183014C539932907 @default.
- W2004183014 hasConceptScore W2004183014C540031477 @default.
- W2004183014 hasConceptScore W2004183014C54582936 @default.
- W2004183014 hasConceptScore W2004183014C55493867 @default.
- W2004183014 hasConceptScore W2004183014C58312451 @default.
- W2004183014 hasConceptScore W2004183014C75473681 @default.
- W2004183014 hasIssue "3" @default.
- W2004183014 hasLocation W20041830141 @default.
- W2004183014 hasOpenAccess W2004183014 @default.
- W2004183014 hasPrimaryLocation W20041830141 @default.
- W2004183014 hasRelatedWork W1978932292 @default.
- W2004183014 hasRelatedWork W1981232136 @default.
- W2004183014 hasRelatedWork W2042344204 @default.
- W2004183014 hasRelatedWork W2047304814 @default.
- W2004183014 hasRelatedWork W2066121771 @default.
- W2004183014 hasRelatedWork W2080217121 @default.
- W2004183014 hasRelatedWork W2081434063 @default.
- W2004183014 hasRelatedWork W2162175307 @default.
- W2004183014 hasRelatedWork W2320083521 @default.
- W2004183014 hasRelatedWork W2951217543 @default.
- W2004183014 hasVolume "60" @default.
- W2004183014 isParatext "false" @default.
- W2004183014 isRetracted "false" @default.
- W2004183014 magId "2004183014" @default.
- W2004183014 workType "article" @default.