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- W2004200148 abstract "The reaction of (Cp‘Ru)3(μ-H)3(μ3-H)2 (1) with a monosubstituted hydrazine such as methylhydrazine and phenylhydrazine results in the exclusive formation of the nonsymmetrically capped bis(μ3-imido) complex (Cp‘Ru)3(μ3-NR)(μ3-NH)(μ-H) (2, R = Me; 3, R = Ph) as a result of cleavage of the nitrogen−nitrogen bond. In contrast to the reaction with monosubstituted hydrazine, the reaction of 1 with 1,2-diphenylhydrazine predominantly yields the monocapped imido complex (Cp‘Ru)3(μ3-NPh)(μ-H)3 (4), due to the steric hindrance between the Cp‘ groups surrounding the reaction site of 1 and the incoming bulky 1,2-diphenylhydrazine. Kinetic studies were carried out to elucidate the reaction mechanism and proved that the methylhydrazine molecule was captured by the Ru3 site from the more nucleophilic −NHMe terminus rather than the less bulky −NH2 terminus. Molecular structures of 2−4 and (Cp‘Ru)3(μ3-NH)2(μ-H) (6) have been determined by means of X-ray diffraction studies." @default.
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- W2004200148 date "2003-01-28" @default.
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- W2004200148 title "Nitrogen−Nitrogen Bond Cleavage of Hydrazine Derivatives by a Trinuclear Pentahydride Complex of Ruthenium, (Cp‘Ru)<sub>3</sub>(μ-H)<sub>3</sub>(μ<sub>3</sub>-H)<sub>2</sub> (Cp‘ = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)" @default.
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- W2004200148 doi "https://doi.org/10.1021/om020755+" @default.
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