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- W2004204086 abstract "The kinetics of the oxidation-reduction of hydrous oxide films formed electrochemically at an Ni + Co-based amorphous alloy in alkaline solutions display numerous similarities with many polymercoated electrodes. In cyclic voltammetric experiments, the anodic response shows a strong dependence on the magnitude and the time spent at negative potentials, particularly in the case of relatively thick films, while the cathodic peak remains essentially unaffected by these variables. Potential step experiments show unusual maxima and peculiar anodic-to-cathodic charge ratios. These results have been explained in terms of ion/solvent injection/expulsion processes which take place during film oxidation-reduction and a disproportionation reaction which occurs within the oxide film under non-steady-state conditions." @default.
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- W2004204086 date "1991-12-01" @default.
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- W2004204086 title "Kinetics of oxidation and reduction of amorphous Ni + Co alloys" @default.
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- W2004204086 doi "https://doi.org/10.1016/0022-0728(91)87081-e" @default.
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