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• W2004226437 abstract "The electronic surface structure of evaporated CuInS2 films with different stoichiometries was investigated by photoelectron spectroscopy [x-ray and ultraviolet (XPS and UPS, respectively)]. The Fermi level position is observed to vary from EF−EV=1.3 eV for the In-rich to EF−EV=0.0 eV for the Cu-rich films. Valence band spectra of In-rich films can be interpreted according to theoretical band structure calculations in the literature. The electronic surface structure of Cu-rich films is determined by a CuS phase segregation which is displayed by an additional valence band emission structure. This phase is responsible for the semimetallic character of the Cu-rich films. A comparison of the energy level positions of Cu-rich and In-rich films is given according to a simple model. The removal of CuS by a KCN treatment is indicated by the complete recovery of the CuInS2 valence band structure. As a consequence highly efficient solar-to-energy conversion can be obtained from CuInS2 films of a wide as-deposited Cu-rich composition range." @default.
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• W2004226437 creator A5051463549 @default.
• W2004226437 date "1994-01-01" @default.
• W2004226437 modified "2023-09-25" @default.
• W2004226437 title "Photoemission study of evaporated CuInS2 thin films. II. Electronic surface structure" @default.
• W2004226437 doi "https://doi.org/10.1116/1.578858" @default.
• W2004226437 hasPublicationYear "1994" @default.
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