Matches in SemOpenAlex for { <https://semopenalex.org/work/W2004243449> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2004243449 endingPage "4130" @default.
- W2004243449 startingPage "4125" @default.
- W2004243449 abstract "Perfluoro substituted organic compounds have attracted attention owing to their unique structure and reactivity induced by the perfluoro effect. Fluoranil, a perfluoro derivative of p-benzoquinone, is the subject of this paper. Although the perfluoro effect in the ground state seems to have been well understood there is no information available about such effects on the excited state. Here, the time-resolved resonance Raman spectra of the triplet excited state of fluoranil are reported along with the Raman excitation profiles (REPs) of the various vibrational modes. The vibrational spectral analyses have been carried out by analogy with the fluoranil ground state, triplet benzoquinone, and triplet chloranil vibrational spectral assignments. Also, the assignments are further supported by the calculated frequencies using abinitio theoretical methods. It is observed that for fluoranil in the triplet excited state, due to the perfluoro effect, the structure is considerably less distorted than benzoquinone and also the electron delocalization in the π* antibonding orbital is less than that of triplet excited state of benzoquinone." @default.
- W2004243449 created "2016-06-24" @default.
- W2004243449 creator A5050130775 @default.
- W2004243449 creator A5090646815 @default.
- W2004243449 date "1997-01-01" @default.
- W2004243449 modified "2023-10-17" @default.
- W2004243449 title "Time-resolved resonance Raman spectroscopic studies on the triplet excited state of fluoranil" @default.
- W2004243449 cites W1965125177 @default.
- W2004243449 cites W1972303778 @default.
- W2004243449 cites W1977239816 @default.
- W2004243449 cites W1978655266 @default.
- W2004243449 cites W1994534461 @default.
- W2004243449 cites W1994785498 @default.
- W2004243449 cites W2024741097 @default.
- W2004243449 cites W2030759183 @default.
- W2004243449 cites W2031385397 @default.
- W2004243449 cites W2052672895 @default.
- W2004243449 cites W2054028305 @default.
- W2004243449 cites W2054467992 @default.
- W2004243449 cites W2060764734 @default.
- W2004243449 cites W2064721253 @default.
- W2004243449 cites W2065428895 @default.
- W2004243449 cites W2066634873 @default.
- W2004243449 cites W2073241980 @default.
- W2004243449 cites W2074496479 @default.
- W2004243449 cites W3004697493 @default.
- W2004243449 cites W308989373 @default.
- W2004243449 doi "https://doi.org/10.1039/a705062c" @default.
- W2004243449 hasPublicationYear "1997" @default.
- W2004243449 type Work @default.
- W2004243449 sameAs 2004243449 @default.
- W2004243449 citedByCount "12" @default.
- W2004243449 countsByYear W20042434492015 @default.
- W2004243449 countsByYear W20042434492022 @default.
- W2004243449 crossrefType "journal-article" @default.
- W2004243449 hasAuthorship W2004243449A5050130775 @default.
- W2004243449 hasAuthorship W2004243449A5090646815 @default.
- W2004243449 hasConcept C120665830 @default.
- W2004243449 hasConcept C121332964 @default.
- W2004243449 hasConcept C139210041 @default.
- W2004243449 hasConcept C147120987 @default.
- W2004243449 hasConcept C178790620 @default.
- W2004243449 hasConcept C181500209 @default.
- W2004243449 hasConcept C184779094 @default.
- W2004243449 hasConcept C185592680 @default.
- W2004243449 hasConcept C189394030 @default.
- W2004243449 hasConcept C40003534 @default.
- W2004243449 hasConcept C41999313 @default.
- W2004243449 hasConcept C62520636 @default.
- W2004243449 hasConcept C69523127 @default.
- W2004243449 hasConcept C70050531 @default.
- W2004243449 hasConcept C75473681 @default.
- W2004243449 hasConcept C76766466 @default.
- W2004243449 hasConcept C83581075 @default.
- W2004243449 hasConcept C95269574 @default.
- W2004243449 hasConceptScore W2004243449C120665830 @default.
- W2004243449 hasConceptScore W2004243449C121332964 @default.
- W2004243449 hasConceptScore W2004243449C139210041 @default.
- W2004243449 hasConceptScore W2004243449C147120987 @default.
- W2004243449 hasConceptScore W2004243449C178790620 @default.
- W2004243449 hasConceptScore W2004243449C181500209 @default.
- W2004243449 hasConceptScore W2004243449C184779094 @default.
- W2004243449 hasConceptScore W2004243449C185592680 @default.
- W2004243449 hasConceptScore W2004243449C189394030 @default.
- W2004243449 hasConceptScore W2004243449C40003534 @default.
- W2004243449 hasConceptScore W2004243449C41999313 @default.
- W2004243449 hasConceptScore W2004243449C62520636 @default.
- W2004243449 hasConceptScore W2004243449C69523127 @default.
- W2004243449 hasConceptScore W2004243449C70050531 @default.
- W2004243449 hasConceptScore W2004243449C75473681 @default.
- W2004243449 hasConceptScore W2004243449C76766466 @default.
- W2004243449 hasConceptScore W2004243449C83581075 @default.
- W2004243449 hasConceptScore W2004243449C95269574 @default.
- W2004243449 hasIssue "23" @default.
- W2004243449 hasLocation W20042434491 @default.
- W2004243449 hasOpenAccess W2004243449 @default.
- W2004243449 hasPrimaryLocation W20042434491 @default.
- W2004243449 hasRelatedWork W1017473139 @default.
- W2004243449 hasRelatedWork W1580753311 @default.
- W2004243449 hasRelatedWork W1984019491 @default.
- W2004243449 hasRelatedWork W1998888077 @default.
- W2004243449 hasRelatedWork W2039937570 @default.
- W2004243449 hasRelatedWork W2057490834 @default.
- W2004243449 hasRelatedWork W2057804588 @default.
- W2004243449 hasRelatedWork W2086485909 @default.
- W2004243449 hasRelatedWork W2191432062 @default.
- W2004243449 hasRelatedWork W4220854239 @default.
- W2004243449 hasVolume "93" @default.
- W2004243449 isParatext "false" @default.
- W2004243449 isRetracted "false" @default.
- W2004243449 magId "2004243449" @default.
- W2004243449 workType "article" @default.