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• W2004245596 abstract "A series of novel ABC2-type liquid-crystalline block copolymers with azobenzene moieties in the side chains were prepared by combination of atom transfer radical polymerization (ATRP) and the chemical modification reaction. First, the bromine-terminated diblock copolymer poly(ethylene oxide) monomethyl ether-block-polystyrene (MPEO-PS-Br) was prepared by ATRP of styrene initiated with macroinitiator MPEO-Br, which was obtained from the esterification of MPEO and 2-bromoisobutyryl bromide. Then, the bromo end groups of the resulting MPEO-PS-Br were derivatized into twice as many bromoisobutyrates by the chain end modification reaction to obtain ω,ω′-bis(bromo)-PS-MPEO (MPEO-PS-Br2). The azobenzene-containing blocks of poly[6-(4-methoxy-azobenzene-4′-oxy) hexyl methacrylate] (PMMAZO) with different molecular weights were introduced into the derivative diblock copolymer by a second ATRP to synthesize the novel ABC2-type liquid-crystalline block copolymers poly(ethylene oxide) monomethyl ether-block-polystyrene-block-{poly[6-(4-methoxy-azobenzene-4′-oxy) hexyl methacrylate]}2 [MPEO-PS-(PMMAZO)2]." @default.
• W2004245596 created "2016-06-24" @default.
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• W2004245596 date "2008-01-01" @default.
• W2004245596 modified "2023-09-26" @default.
• W2004245596 title "Novel ABC2-type liquid-crystalline block copolymers with azobenzene moieties prepared by atom transfer radical polymerization" @default.
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• W2004245596 doi "https://doi.org/10.1016/j.eurpolymj.2007.11.003" @default.
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