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• W2004246166 abstract "The pressure and temperature dependences of association reactions involving atoms and/or radicals is discussed and illustrated by reference to the reactions CH3 + CH3 → C2H6, CH3 + O2 → CH3O2, CH3 + H → CH4, and H + C2H4 → C2H5. Recent experimental measurements of the rate coefficients, k([M], T) are described, particular attention being paid to experiments designed to measure the rate coefficient over wide ranges of pressure and temperature. Methods of fitting the experimental data, to obtain estimates of the limiting rate coefficients, k0 and k∞, and to permit extrapolation to regions beyond the experimental range, are discussed. These methods include the Troe factorization technique, a combination of master equation and variational RRKM theory, and recent calculations by Wagner and Wardlaw using the technique developed by Wardlaw and Marcus to describe loose transition states." @default.
• W2004246166 created "2016-06-24" @default.
• W2004246166 creator A5024382257 @default.
• W2004246166 date "1989-04-01" @default.
• W2004246166 modified "2023-09-26" @default.
• W2004246166 title "Association reactions of atoms and radicals" @default.
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• W2004246166 doi "https://doi.org/10.1002/kin.550210406" @default.
• W2004246166 hasPublicationYear "1989" @default.
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