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- W2004247712 abstract "Cinchona-based primary amine-catalyzed cascade aza-Michael–aldol reactions of α,β-unsaturated ketones with 2-(1H-pyrrol-2-yl)-2-oxoacetates provided highly functionalized chiral pyrrolizines bearing multistereocenters including a chiral quaternary carbon center in good yields (up to 92%) with excellent levels of stereocontrol (90–95% ee, >20:1 dr in all cases). The ketone group in the cascade product was asymmetrically reduced to chiral secondary hydroxyl groups in good yields." @default.
- W2004247712 created "2016-06-24" @default.
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- W2004247712 date "2013-02-27" @default.
- W2004247712 modified "2023-09-23" @default.
- W2004247712 title "Cinchona-Based Primary Amine-Catalyzed Asymmetric Cascade Aza-Michael–Aldol Reactions of Enones with 2-(1<i>H</i>-Pyrrol-2-yl)-2-oxoacetates: Synthesis of Chiral Pyrrolizines with Multistereocenters" @default.
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- W2004247712 doi "https://doi.org/10.1021/jo4001614" @default.
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