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- W2004248361 abstract "Although obtained by different methods the cluster [(PPh3)Pd(AuPPh3)6]2+ was always collected as a microcrystalline product. Attempts to get crystals of this cluster for X-ray determination were successfully made changing the counter-ion NO3 − to PF6 −. This new compound was characterized by elemental analysis, IR, and 31P NMR spectroscopy in solution. The crystal and molecular structure was determined by a single crystal X-ray analysis. The compound crystallizes in the triclinic space group P1̄ with a=17.138 (3) Å, b=27.263 (5) Å, c=27.543 (6) Å, α=101.70 (3)°, β=105.80 (3)°, γ=90.19 (3)° T=273 °C, Z=4, V=12 102 Å3, R=0.1149 and Rw=0.2669 for 23 620 observations. The structure consists of part of an icosahedron Pd centered. The Pd atom is bound to one PPh3 molecule and six gold atoms. The PPh3 is attached to the gold atom and the structure is isoelectronic and isostructural to the [(PPh3)Pt(AuPPh3)6]2+ cluster." @default.
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- W2004248361 date "2003-05-01" @default.
- W2004248361 modified "2023-10-11" @default.
- W2004248361 title "Synthesis, characterization, X-ray crystal and molecular structure of [(PPh3)Pd(AuPPh3)6](PF6)2" @default.
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- W2004248361 doi "https://doi.org/10.1016/s0020-1693(02)01476-7" @default.
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