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• W2004248614 abstract "Nuclear quadrupole resonances have been measured for both 63Cu and 65Cu nuclei in the Cu[(CH3)3PS]3+ cations of both the perchlorate and tetrafluoroborate compounds. The 63Cu resonances are at 24.815 ± 0.001 MHz and 24.838 ± 0.001 MHz, respectively, indicating that the anion contributes little to the electric field gradient tensor. An extended Hückel molecular orbital calculation was used to calculate coupling constants which agreed with experiment to within a factor of 3. The difference can be accounted for on the basis of the use of a Slater type basis set of orbitals and the variation of the Sternheimer factor with the charge on the copper atom." @default.
• W2004248614 created "2016-06-24" @default.
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• W2004248614 date "1975-11-01" @default.
• W2004248614 modified "2023-09-27" @default.
• W2004248614 title "Nuclear quadrupole coupling in copper(I) coordination compounds. Tris(trimethylphosphinesulfide)copper(I) ion" @default.
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• W2004248614 doi "https://doi.org/10.1016/0022-2364(75)90261-9" @default.
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