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- W2004248913 abstract "The lipase catalyzed enantiomeric resolution of syn-glycol was carried out to confirm the sector method, which can determine the absolute configuration of anti- and syn-glycol from the 1H-NMR spectra of bis-2-methoxy-2-trifluoromethyl-2-phenylacetic acid (MTPA) esters. The lipase catalyzed transesterification reaction was most reactive at the C2 position (C2–OH) of (2R;3R)-2,3-octanediol. Both (2S;3S)- and (2R;3R)-2,3-octanediol were prepared using lipase. The 1H-NMR spectra of their bis-(R)-MTPA esters agreed well with those prepared previously via mono-(R)-MTPA esters. The result suggests the retention of the Mosher plane in MTPA esters possessing a hydroxyl group at the β position. The reaction rate and the stereoselectivity decreased at C2–OH with the addition of 18-crown-6. Chirality 11:338–342, 1999. © 1999 Wiley-Liss, Inc." @default.
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- W2004248913 date "1999-01-01" @default.
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- W2004248913 title "Enantiomeric resolution of asymmetric glycol by a lipase-catalyzed transesterification reaction" @default.
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- W2004248913 doi "https://doi.org/10.1002/(sici)1520-636x(1999)11:4<338::aid-chir13>3.0.co;2-q" @default.
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