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- W2004268107 abstract "The synthesis of (22R)-22-hydroxycholesterol, featuring formation of three contiguous chiral centers (C-17, 20, and 22) in a single step by the use of a 6-endo α-silyl radical-mediated cyclization is presented. Additionally, an interesting protiodesilylation used to activate a cyclic siloxane towards C–Si bond oxidation, and a modified, bulky aryl thionocaronate reagent for regioselective diol-monodeoxygenation are described." @default.
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- W2004268107 date "1990-01-01" @default.
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- W2004268107 title "Stereocontrolled Synthesis of (22<i>R</i>)-22-Hydroxycholesterol Guided by α-Silyl Radical Stabilization" @default.
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- W2004268107 doi "https://doi.org/10.1246/cl.1990.83" @default.
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